osmolar gap

The osmolar gap is a diagnostic tool which can help identify the presence of some foreign solute in the body fluids. In the CICM fellowship SAQs, it mostly identifies young women who have ingested a toxic alcohol.

definition

difference between measured osmolality and calculated, i.e. (2× Na+ + glucose + urea)
(in UK units, if it matters)

  • not to be taken literally mathematically - different units

Normal <10

what's it caused by?

Normal anion gap and high osmolar gap

implies a solute (i.e. osmotically active) that does not dissociate at physiological pH
therefore this includes:

  • glycine (TURP syndrome)
  • polyethylene glycol (in some IV meds including lorazepam)
  • soon after ethylene glycol, methanol intoxication (see the deranged physiology link)
  • mannitol, sorbitol

high anion gap AND high osmolar gap

→ What is the anion?

  • Toxicological causes
    • Methanol intoxication (the anion is formic acid)
    • Ethylene glycol intoxication (the anions are glycolic acid and oxalic acid)
    • Diethylene glycol intoxication (the anion is 2-hydroxyethoxyacetic acid, HEAA)
    • Propylene glycol intoxication (the anions are pyruvate, lactate and acetate)
    • Salicylate intoxication (the anions are salicylate and lactate)
    • Any toxin causing massive lactic acidosis, eg. isoniazid
  • Endocrine and metabolic disturbances